You can set up Skype for Business to forward your calls all the time or during work hours as set in Outlook.
In the Call Forwarding – Time Setting window, select All the time, or During work hours set in Outlook.
To change your work days and times in Outlook, do the following:
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In your Outlook calendar, click the File tab, then Options > Calendar.
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Under Work time:
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Choose the Start time and End time of your work day.
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Select the days of the week that you work, and clear the days that are not a part of your work week.
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Choose the First day of the week that you start working.
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To change the first week of the year, choose an option in the First week of year list.
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Click OK to confirm the changes.
For more information about call forwarding, see Set Call Forwarding options.