With a template
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On the File tab, click New.
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In the Search for online templates and themes box, type org chart, then click the magnifying glass icon.
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Choose an org chart from the search results.
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Click Create.
With SmartArt
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On the Insert tab, in the Illustrations group, click SmartArt.
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In the Choose a SmartArt Graphic gallery, click Hierarchy.
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Click an organization chart layout (such as Organization Chart), then click OK.